You are using a 32bit version of NCryptoki in your VS2012 64bit application.
If you compile your app for AnyCPU it runs as 64bit application and cannot load a 32bit dll.
you can either:
1) Change your target cpu to x86 and use the 32bit version of the underlyin PKCS#11 dll
or
2) use the 64bit version of NCryptoki. you will find it in the sdk folder